A review of per- and polyfluoroalkyl substances (PFASs) removal in constructed wetlands: Mechanisms, enhancing strategies and environmental risks

Per: Polyfluoroalkyl substances (PFASs), typical persistent organic pollutants detected in various water environments, have attracted widespread attention due to their undesirable effects on ecology and human health. Constructed wetlands (CWs) have emerged as a promising, cost-effective, and nature-based solution for removing persistent organic pollutants. This review summarizes the removal performance of PFASs in CWs, underlying PFASs removal mechanisms, and influencing factors are also discussed comprehensively. Furthermore, the environmental risks of PFASs-enriched plants and substrates in CWs are analyzed. The results show that removal efficiencies of total PFASs in various CWs ranged from 21.3% to 98%. Plant uptake, substrate absorption and biotransformation are critical pathways in CWs for removing PFASs, which can be influenced by the physiochemical properties of PFASs, operation parameters, environmental factors, and other pollutants. Increasing dissolved oxygen supply and replacing traditional substrates in CWs, and combining CWs with other technologies could significantly improve PFASs removal. Further, CWs pose relatively lower ecological and environmental risks in removing PFASs, which indicates CWs could be an alternative solution for controlling PFASs in aquatic environments.