Catalytic mechanisms of nickel nanoparticles for the improved dehydriding kinetics of magnesium hydride

MgH2 , albeit with slow desorption kinetics, has been extensively studied as one of the most ideal solid hydrogen storage materials. Adding such catalyst as Ni can improve the desorption kinetics of MgH2 , whereas the catalytic role has been attributed to different substances such as Ni, Mg2 Ni, Mg2 NiH0.3 , and Mg2 NiH4 . In the present study, Ni nanoparticles (Ni-NPs) supported on mesoporous carbon (Ni@C) have been synthesized to improve the hydrogen desorption kinetics of MgH2 . The utilization of Ni@C largely decreases the dehydrogenation activation energy from 176.9 to 79.3 kJ mol-1 and the peak temperature of dehydrogenation from 375.5 to 235 degrees C. The mechanism of Ni catalyst is well examined by advanced aberration-corrected environmental transmission electron microscopy and/or x-ray diffraction. During the first dehydrogenation, detailed microstructural studies reveal that the decomposition of MgH2 is initially triggered by the Ni-NPs, which is the rate-limiting step. Subsequently, the generated Mg reacts rapidly with Ni-NPs to form Mg2 Ni, which further promotes the dehydrogenation of residual MgH2 . In the following dehydrogenation cycle, Mg2 NiH4 can rapidly decompose into Mg2 Ni, which continuously promotes the decomposition of MgH2 . Our study not only elucidates the mechanism of Ni catalyst but also helps design and assemble catalysts with (c) 2023 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University