Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

被引：1
作者：
Clark, Ella F. [1 ]
Dunstan, Estelle [1 ]
Kociok-Kohn, Gabriele [2 ]
Buchard, Antoine [3 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, England
[2] Univ Bath, Mat & Chem Characterisat Facil, Bath, England
[3] Univ York, Dept Chem, York YO10 5DD, England
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 89期
关键词：
ALTERNATING COPOLYMERIZATION; PHTHALIC-ANHYDRIDE; CARBON-DIOXIDE; POLYESTERS; OXIDE; POLYMERIZATION; PORPHYRIN; CATALYSTS; ROCOP;
D O I：
10.1039/d4cc03947e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator. The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation (ROCOP) of CHO/PA without the need for a co-initiator.
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页码：13067 / 13070
页数：4
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