A transition-metal-free catalytic reduction of benzylic alcohols and alkenes and N-formylation of nitroarenes mediated by iodide ions and formic acid

被引：0

作者：

Wang, Yufen ^{[1
]}

Wang, Yantao ^{[2
]}

Ma, Yongqing ^{[2
]}

Elsharif, Asma Mohmmad ^{[3
]}

Zhang, Chen ^{[1
]}

Yang, Weiran ^{[2
]}

Len, Christophe ^{[4
,5
]}

机构：

[1] NanChang Univ, Sch Resources & Environm, 999 Xuefu Rd, Nanchang 330031, Peoples R China

[2] NanChang Univ, Sch Chem & Chem Engn, 999 Xuefu Rd, Nanchang 330031, Peoples R China

[3] Imam Abdulrahman Bin Faisal Univ, Coll Sci, Dept Chem, Dammam 31441, Saudi Arabia

[4] Xi An Jiao Tong Univ, Sch Chem, 28 Xianning West Rd, Xian 710049, Peoples R China

[5] PSL Res Univ, Inst Chem Life & Hlth Sci, Chim ParisTech, CNRS, F-75005 Paris, France

来源：

NEW JOURNAL OF CHEMISTRY | 2024年 / 48卷 / 47期

基金：

中国国家自然科学基金;

关键词：

TRANSFER HYDROGENATION; TRANSFER HYDROGENOLYSIS; GAMMA-VALEROLACTONE; NITRO-COMPOUNDS; HYDRIODIC ACID; DOPED CARBON; EFFICIENT; GLYCEROL; NANOPARTICLES; NITROBENZENE;

D O I：

10.1039/d4nj03772c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new transition-metal-free catalytic system which uses sodium iodide as the catalyst with formic acid as the hydrogen donor in a biphasic medium was reported for the reduction of the hydroxyl group and various unsaturated groups such as C 00000000 00000000 00000000 00000000 11111111 00000000 11111111 00000000 00000000 00000000 C, C 00000000000000000 00000000000000000 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 00000000000000000 00000000000000000 C, CN and CO. Using the same catalytic system, reductive N-formylation of nitroarenes with formic acid was explored to produce the corresponding amide in high selectivity. Moreover, the catalyst stability was evaluated and reaction mechanisms were studied and proposed for the three model reactions.

引用

页码：20041 / 20050

页数：10

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