Morphology and line tension of twist disclinations in a nematic liquid crystal

被引:0
作者
Chen, Yihao [1 ]
Mandic, Mina [2 ]
Slaughter, Charlotte G. [1 ]
Tanaka, Michio [1 ]
Kikkawa, James M. [1 ]
Collings, Peter J. [1 ,2 ]
Yodh, A. G. [1 ]
机构
[1] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
[2] Swarthmore Coll, Dept Phys & Astron, Swarthmore, PA 19081 USA
基金
美国国家科学基金会;
关键词
ELASTIC-CONSTANTS; FIELD; ORDER;
D O I
10.1039/d4sm01076k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We deploy optical microscopy with and without an applied magnetic field to characterize the three-dimensional morphology and measure the line tension of twist disclinations in twisted nematic liquid crystal (LC) sample cells. Twist disclinations are generated by quenching the LC, 5CB (4-cyano-4 '-pentylbiphenyl), into the nematic phase; 5CB is confined between substrates with in-plane anchoring directions perpendicular to one another. The disclinations form loops separating domains of opposite twist handedness. Many segments of these loops are pinned to the substrates, and the ends of some pinned segments connect to free disclination segments that penetrate into the bulk nematic. We use confocal microscopy to measure the profiles of these free disclinations and test theoretical predictions about their shape, yielding a lower bound of similar to 32 nm for the disclination core radius. We then use an applied magnetic field to deform the free disclinations into circular arcs whose curvature increases with magnetic field strength and depends on the field-induced energy difference between opposite twist domains. The line tension of the disclinations is derived from an energy-balance equation that relates disclination curvature to magnetic field. The measured line tension increases logarithmically with sample cell thickness; it ranges from 75 to 200 pN in samples with thickness spanning from 6 to 27 mu m. In total, the investigation introduces new non-invasive methodologies for studies of defects in LCs, and it provides new information about the line tension and character of isolated twist disclinations, thereby testing theory and laying experimental foundation for the study of ensembles of disclinations.
引用
收藏
页码:9050 / 9059
页数:10
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