An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

被引：0

作者：

Bilyachenko, Alexey N. ^{[1
,2
]}

Khrustalev, Victor N. ^{[1
,3
]}

Huang, Zhibin ^{[2
]}

Shul'pina, Lidia S. ^{[1
]}

Dorovatovskii, Pavel V. ^{[4
]}

Shubina, Elena S. ^{[1
]}

Ikonnikov, Nikolay S. ^{[1
]}

Lobanov, Nikolai N. ^{[2
]}

Ragimov, Karim ^{[5
]}

Sun, Di ^{[6
]}

机构：

[1] Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia

[2] RUDN Univ, Peoples Friendship Univ Russia, 6 Miklukho Maklaya St, Moscow 117198, Russia

[3] Russian Acad Sci, Zelinsky Inst Organ Chem, 47 Leninsky Prospect, Moscow 119991, Russia

[4] Natl Res Ctr, Kurchatov Inst, 1 Akad Kurchatova Pl, Moscow 123182, Russia

[5] Baku State Univ, Z Xalilov Str 23, Baku 1148, Azerbaijan

[6] Shandong Univ, Sch Chem & Chem Engn, Shanda South Rd 27, Jinan 250100, Peoples R China

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 48期

基金：

俄罗斯科学基金会;

关键词：

Chelation; -; Synthesis; (chemical);

D O I：

10.1039/d4dt02690j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first metallasilsesquioxane bearing pyrazolylpyridine ligands, the Cu8-based complex 1, adopts a cage-like structure with two zigzag-type copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. The four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual (chelating and bridging) modes of ligation. Compound 1 is very active in the oxidation of alkanes and alcohols.

引用

页码：19102 / 19106

页数：5

共 59 条

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