A novel Yb2SiO5 ceramic aerogel with excellent thermal stability for high-temperature thermal insulation

被引:2
作者
Shang, Sisi [1 ,2 ]
Wang, Jie [1 ,2 ]
Wang, Zihan [1 ,2 ]
Song, Zihao [1 ,2 ]
Yuan, Man [1 ,2 ]
You, Qi [1 ,2 ]
Ge, Longhui [1 ,2 ]
Yang, Jian [1 ,2 ]
Cui, Sheng [1 ,2 ]
机构
[1] Nanjing Tech Univ, Coll Mat Sci & Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China
[2] Jiangsu Collaborat Innovat Ctr Adv Inorgan Funct C, Nanjing 211816, Peoples R China
基金
中国国家自然科学基金;
关键词
Ceramic aerogel; Rare earth monosilicate; Thermal stability; Thermal insulation; SILICA AEROGEL; MECHANICAL-PROPERTIES; Y2SIO5; CERAMICS; PARTICLE-SIZE; CONDUCTIVITY; COMPOSITES; ADSORPTION; DEPOSITION; STRENGTH;
D O I
10.1016/j.ceramint.2024.09.359
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To investigate the potential of rare earth oxide structural ceramics for high-temperature insulation applications, we introduced aerogel structures into Yb2SiO5 ceramics. In this study, the pure Yb2SiO5 ceramic aerogels were successfully prepared by calcination using formamide as a gelling agent, the sol-gel method, and the CO2 supercritical drying method. The results indicate that the Yb2SiO5 ceramic aerogel exhibits exceptional structural and phase stability at a temperature of 1400 degrees C. In addition, we have developed Yb2SiO5 ceramic aerogel composites reinforced with aluminosilicate fiber cotton, which exhibit low density (228.77 kg m-3) and low thermal conductivity (0.038 W m- 1 K- 1 at 25 degrees C, 0.102 W m- 1 K- 1 at 1000 degrees C). The back temperature of the 10 mm thick composites is only 285 degrees C after exposure to a butane blowtorch flame at 1300 degrees C for 600 s. This demonstrates its excellent high-temperature insulation performance. This work can provide a basis for further design and preparation of oxide ceramic high-temperature thermal protection materials with controllable morphology and properties.
引用
收藏
页码:50133 / 50144
页数:12
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