Rhodium-catalyzed synthesis of Si-stereogenic alkoxysilanes and silyl enol ethers via hydrosilylation of carbonyl compounds

被引：1

作者：

Ding, Yang ^{[1
,2
]}

Ke, Jie ^{[1
,2
]}

Zhang, Wenbin ^{[4
]}

Li, Bin ^{[3
]}

He, Chuan ^{[1
,2
]}

机构：

[1] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

[2] Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

[3] Wuyi Univ, Sch Environm & Chem Engn, Jiangmen 529020, Guangdong, Peoples R China

[4] Guangdong Wamo New Mat Technol CO LTD, Jiangmen 529020, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 93期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC HYDROSILYLATION; SILICON; KETONES; CONSTRUCTION; SILANES; IMINES;

D O I：

10.1039/d4cc05360e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient rhodium-catalyzed asymmetric hydrosilylation of aldehydes, ketones, and alpha,beta-unsaturated ketones with dihydrosilanes is developed, that allows the rapid assembly of a variety of Si-stereogenic alkoxysilanes and silyl enol ethers in good yields and enantioselectivities under mild conditions. The applicability of this methodology was demonstrated by a series of stereospecific transformations to construct diverse Si-stereogenic derivatives.

引用

页码：13734 / 13737

页数：4

共 18 条

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[9] Synthesis of Ethers from Carbonyl Compounds by Reductive Etherification Catalyzed by Iron(III) and Silyl Chloride
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