Controllable assembly over two CoII-based coordination polymers: structures and catalytic properties towards the alkene oxyalkylation reaction

被引:1
作者
Xu, Li-Mei [1 ]
Wang, Qian [1 ]
Zhang, Lin [2 ]
Shen, Jin-Qiu [1 ]
Chen, Xiao-Lu [1 ]
Zhang, Jian-Yong [1 ]
Liu, Zhen-Jiang [1 ]
机构
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
[2] Fuyang Normal Univ, Sch Chem & Mat Engn, 100 Qinghe West Rd, Fuyang 236041, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; CHEMISTRY; LIGANDS;
D O I
10.1039/d4ce00857j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two CoII-coordination polymers were controllably obtained by the solvothermal reaction of C-3 symmetric 5-bromo-1,3-benzenedicarboxylic acid (Br-1,3-H2BDC), 4,4 ',4 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)tripyridine (4-TMTBT) ligand, and CoII salts. Co-CP-1 displayed a 3D net based on a mononuclear CoII center linked by Br-1,3-BDC2- and 4-TMTBT mixed ligands. Co-CP-2 featured a 3D network based on a trinuclear Co-3(mu(3)-OH)(HCOO)(COO)(4) unit and Br-1,3-BDC2- and 4-TMTBT ligands, which could be regarded as a new (3,7)-connected topology net. Interestingly, the two Co-CPs showed good catalytic activities for the alkene oxyalkylation reaction. In particular, Co-CP-2 exhibited higher catalytic performance and could be recycled at least for four cycles without loss of activity and structural integrity.
引用
收藏
页码:6134 / 6142
页数:9
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