Selective electroreduction of acetylene to 1,3-butadiene on iodide-induced Cuδ+-Cu0 sites

A crucial task towards creating a sustainable chemical industry is the electrification of chemical processes that produce value-added molecules. One such molecule is 1,3-butadiene (1,3-BD), the feedstock used for manufacturing synthetic rubber. 1,3-BD is traditionally derived, as a by-product, during the energy-intensive steam cracking of naphtha to ethylene. Here we introduce an alternative approach to selectively produce 1,3-BD from the electroreduction of acetylene (e-C2H2R). By using a potassium iodide electrolyte, we created Cu delta+-Cu0 sites on a Cu2O-nanocube-derived catalyst, which are efficacious for promoting e-C2H2R to 1,3-BD. 1,3-BD was formed with a Faradaic efficiency reaching 93% at -0.85 V versus standard hydrogen electrode (SHE) and a partial current density of -75 mA cm-2 at -1.0 V versus SHE. Density functional theory calculations show that I- preserves Cu delta+-Cu0 sites, which facilitate the favourable binding of acetylene, leading to 1,3-BD formation through the coupling of *C2H3 moieties. Electrifying energy-intensive processes is a promising approach for decarbonization. Now, 1,3-butadiene is electrochemically produced from acetylene on I--induced Cu delta+-Cu0 sites with a Faradaic efficiency of over 90% at -0.85 VSHE and a partial current density of -75 mA cm-2 at -1.0 VSHE.