Effect of Cr Doping on the Preferred Orientation and Frictional Properties of TiAlN Coatings

被引:0
作者
Zhang, Ergeng [1 ]
Liu, Jiang [1 ]
Cai, Yuanfei [2 ]
Liang, Dandan [1 ]
Chen, Qiang [1 ]
Zhou, Qiong [1 ]
Huang, Biao [1 ]
机构
[1] Shanghai Engineering Technology Research Center of Physical Vapor Deposition (PVD) Superhard Coatings and Equipment, Shanghai Institute of Technology, Shanghai
[2] School of Materials Science and Engineering, Tongji University, Shanghai
来源
Cailiao Daobao/Materials Reports | 2024年 / 38卷 / 24期
基金
中国国家自然科学基金; 上海市自然科学基金;
关键词
Cr doping; mechanical property; preferred orientation; TiAlCrN coating; wear;
D O I
10.11896/cldb.23080252
中图分类号
学科分类号
摘要
To improve the mechanical properties and wear resistance of TiAlN coatings, TiAlCrN coatings with various Cr contents were deposited on 316 L stainless steel via cathodic arc technology. The effect of Cr doping on the microstructure and mechanical properties of the coatings was investigated, and the wear mechanism of the coatings was also revealed. The results showed that TiAlCrN coatings had cubic structure and grew along the (200), (111), (220), and (311) crystal planes. Besides, the texture coefficient of the grains along the (111) crystal plane increased with the Cr target current, namely, Cr doping could promote the optimal growth of the coating along (111) crystal surface. As the Cr target current raised, the hardness and bonding force of TiAlCrN coatings were enhanced, but the coefficient of friction and wear rate of TiAlCrN coatings were decreased. The coating with a Cr target current of 150 A showed the maximum hardness (25. 50 GPa) and bonding force (26. 97 N), as well as the lowest friction coefficient (0. 26) and wear rate (1. 87× 10-5 mm3·N-1·m-1). The main wear mechanisms of TiAlCrN coatings were abrasive, oxidative, and adhesive wear. Meanwhile, TiAlCrN coatings with high Cr target current exhibited a relatively low wear rate, because CrOx with better lubrication properties, was preferentially formed over TiOx and AlOx during the friction wear process. Moreover, Cr doping could effectively ameliorate the spalling phenomenon, thus further strengthening the mechanical and friction wear performance of TiAlCrN coatings. © 2024 Cailiao Daobaoshe/ Materials Review. All rights reserved.
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共 36 条
  • [1] Tian B, Yue W, Wang C, Et al., Applied Surface Science, 353, (2015)
  • [2] Serag E, Caers B, Schuurmans P, Et al., Surface and Coatings Technology, 441, (2022)
  • [3] Zhang B, Zhu S, Wang Z, Et al., Materials Letters, 169, (2016)
  • [4] Jung D H, Moon K I, Shin S Y, Et al., Thin Solid Films, 546, (2013)
  • [5] Huang B, Zhou Q, An Q, Et al., Surface and Coatings Technology, 429, (2022)
  • [6] Tu J, Duan H, Xu J, Et al., Science China Technological Sciences, 57, 2, (2014)
  • [7] Yuan J, Yamamoto K, Covelli D, Et al., Surface and Coatings Technology, 294, (2016)
  • [8] Beake B D, Isern L, Endrino J L, Et al., Wear, 418-419, (2019)
  • [9] Fox-rabinovich G S, Yamomoto K, Veldhuis S C, Et al., Surface and Coatings Technology, 200, 5-6, (2005)
  • [10] Xu Y X, Chen L, Yang B, Et al., Surface and Coatings Technology, 235, (2013)