Kinetics of crotonaldehyde hydrogenation over a titania-supported platinum catalyst

被引:0
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作者
Makouangou, Romuald M. [1 ]
Murzin, Dimitri Y. [1 ]
Dauscher, Anne E. [1 ]
Touroude, Raymonde A. [1 ]
机构
[1] CNRS-ULP-EHICS, Strasbourg, France
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Aldehydes - Catalyst selectivity - Catalyst supports - Catalysts - Hydrogenation - Mathematical models - Platinum - Reaction kinetics - Titanium dioxide;
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摘要
Crotonaldehyde hydrogenation is a complex reaction that has been modeled using results from a standard gas flow system. The obtained results give rise to the formation of a reaction network and an elementary step mechanism derived from steady-state kinetics. The selectivity of the system to give crotyl alcohol is explained in terms of the surface electronic gas model.
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页码:1881 / 1888
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