1,2,4-Triazine N-oxides and their annelated derivatives

被引：0
|
作者：
Kozhevnikov, D.N. [1 ]
Chupakhin, O.N. [1 ]
机构：
[1] Ural State Technical University, ul. Mira 19, 620002 Ekaterinburg, Russia
来源：
Russian Chemical Reviews | 1998年 / 67卷 / 08期
关键词：
Physical chemistry;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review deals with the synthesis and properties of 1,2,4-triazine N-oxides and their annelated derivatives. Methods for the incorporation of the N-oxide group in the 1,2,4-triazine ring by direct oxidation and cyclisation involving nitro, nitroso, and isonitroso groups are discussed. Reactions of 1,2,4-triazine N-oxides with electrophiles, nucleophiles, and dicnophilcs are considered. The effect of the N-oxide group on the chemical shifts in the 1H, 13C, and 14N NMR spectra and the specific features of decomposition of 1,2,4-triazine N-oxides under elec-tron impact are analysed. © 1998 Russian Academy of Sciences and Turpion Ltd.
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页码：633 / 648
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