Effect of network morphology on adhesive performance in emulsion blends of acrylic pressure sensitive adhesives

High-gel containing latices and gel-free latex were blended at various weight ratios. The high-gel containing latices was made of poly(2-ethyl hexylacrylate-stat-acrylic acid) and the gel-free latex was made of poly(2-ethyl hexylacrylate-stat-acrylic acid-stat-isobutoxymethyl acrylamide) using semicontinuous emulsion polymerization. Films were cast at room temperature and dried at 121°C for 10 min. Adhesive performance was evaluated in terms of loop tack, peel, and shear holding power. It was found that interlinking the microgels by the linear polymer due to the isobutoxymethyl acrylamide-acrylic acid reaction in the film when heated gave synergistic effects in increasing shear. This interlinking could take place only if the molecular weight between crosslinks (Mc) of the microgels was greater than the entanglement molecular weight of the linear polymer (Me), and if the weight average molecular weight of the linear polymer (Mw) was greater than 2 × Me. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci.