Friedel-Crafts reaction of toluene with oxalyl chloride

被引：0

作者：

Sakaino, Y. ^{[1
]}

Sugawara, K. ^{[1
]}

Terao, Y. ^{[1
]}

Fujiwara, T. ^{[1
]}

Mori, Y. ^{[1
]}

Maeda, K. ^{[1
]}

机构：

[1] Gunma Univ, Maebashi, Japan

来源：

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | 1996年 / 276-277卷 / pt 1-2期

关键词：

Addition reactions - Decomposition - Derivatives - Fluorescence - Fluorine compounds - Friedel-Crafts reaction - Mixing - Naphthalene - Phosphorescence - Solid state physics - Solutions - Structure (composition);

D O I：

暂无

中图分类号：

学科分类号：

摘要：

By the Friedel-Crafts reaction of toluene with oxalyl chloride, three kinds of fluorene derivatives (c, d, e), naphthalene derivative f, fluorenone derivative g, were obtained in addition to 4,4′-dimethyl benzophenone b.. In the compounds (c, d, e, f, g), c shows thermochromism above 135°C in solution, while e emits phosphorescence and f exhibits fluorescence at room temperature in the solid states.

引用

页码：271 / 275