Local order and H-bonding in N-rich amorphous silicon nitride

被引:6
作者
Senemaud, C. [1 ]
Gheorghiu, A. [1 ]
Amoura, L. [1 ]
Etemadi, R. [1 ]
Shirai, H. [1 ]
Godet, C. [1 ]
Fang, M. [1 ]
Gujrathi, S. [1 ]
机构
[1] CNRS, Paris, France
关键词
Chemical vapor deposition - Lattice vibrations - Silicon nitride - Solid state physics;
D O I
10.1016/0022-3093(93)91184-5
中图分类号
学科分类号
摘要
The local order in Plasma-Enhanced Chemical Vapor Deposition (PECVD) N-rich a-SiNx:H films is shown to depend strongly on the H bonding configuration. The Si-H bonding affects the Si-N lattice vibration, giving a shoulder at 1020 cm-1, and shifts the Si3p - N2p peak position in the valence band distribution towards lower binding energies.
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页码:1073 / 1076
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