Raman Spectra of Cu/Zn Superoxide Dismutase and L-cysteine Used as an Electron Transfer Promoter

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作者
Cao, Xiaowei [1 ]
Meng, Xiaoyun [1 ]
Yang, Haifeng [1 ]
Wu, Xiaqin [1 ]
Wang, Guihua [1 ]
Zhang, Zongrang [1 ]
机构
[1] Department of Chemistry, Shanghai Teachers University, 200234 Shanghai, China
来源
Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis | 2001年 / 21卷 / 04期
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摘要
In author's laboratory,it has been demonstrated with electrochemical techniques that L-cysteine can be used as an effective electron transfer promoter to accelerate the electron transfer process of Cu/Zn superoxide dismutase on gold electrode. In order to reveal the mechanism of this promotion,confocal microscopic Raman spectroscopic technique is employed here to obtain Raman spectra of solid state SOD and L-cysteine modified gold electrode. Moreover,Raman spectra of L-cysteine modified gold electrode with two different approaches are also obtained. Analysis and discussion for these Raman spectra are reported.
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页码:487 / 488
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