Epitaxial growth of single-crystal ultrathin films of bismuth on Si(111)

被引:0
作者
Nagao, Tadaaki [1 ,2 ]
Doi, Takumi [1 ]
Sekiguchi, Takeharu [1 ]
Hasegawa, Shuji [1 ,2 ]
机构
[1] Department of Physics, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
[2] Core Res. Evolutional Sci. Technol., Japan Sci. and Technol. Corporation, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
来源
Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers | 2000年 / 39卷 / 7 B期
关键词
Crystal defects - Crystal orientation - Epitaxial growth - Nanostructured materials - Reflection high energy electron diffraction - Scanning tunneling microscopy - Semiconducting bismuth compounds - Semiconducting silicon - Semiconductor growth - Single crystals - Ultrathin films - Wetting;
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摘要
We have studied the epitaxial growth of bismuth overlayers on Si(111) surfaces by in situ reflection high-energy electron diffraction (RHEED) and scanning tunneling microscopy (STM). Lateral growth of texture two-dimensional (2D) nanocrystals takes place after the formation of an initial disordered wetting layer on the 7×7 DAS structure. After the coalescence of the texture 2D nanocrystals, alignment in their azimuthal orientation takes place. At slightly more than 15 monolayers, the growth front of the overlayer exhibits a perfectly long-range ordered Bi(0001)-1×1 surface. The films prepared on Si(111)-α-√3×√3-Bi or on Si(111)-β-√3×√3-Bi do not show as good quality as those on Si(111)-7×7. Thus, the initial disordered wetting layer formed on the 7×7 surface successfully accommodates the large 18% lattice mismatch between the Si(111) and Bi(0001) planes and allows the 2D nanocrystal to grow laterally.
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页码:4567 / 4570
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