Etherification of 2-methylpropene, 2-methyl-1-butene and 2-methyl-2-butene with alcohols

被引：0

作者：

Linnekoski, Juha A. ^{[1
]}

机构：

[1] Helsinki University of Technology, Department of Chemical Technology, Laboratory of Industrial Chemistry, P.O. Box 6100, FIN-02015 HUT, Finland

来源：

Acta Polytechnica Scandinavica, Chemical Technology Series | 1999年 / 271期

关键词：

Alcohols - Butenes - Catalysis - Ion exchange resins - Isomerization - Positive ions - Propylene - Reaction kinetics - Water;

D O I：

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学科分类号：

摘要：

The etherification of isobutene, 2-methyl-1-butene and 2-methyl-2-butene (isoamylenes) with various alcohols was studied using a strong cation exchange resin as catalyst. Main emphasis was on the determination of the reaction equilibria and on kinetic modeling. The effect of water on the etherification and isomerization of isoamylenes was studied in addition to the dehydration of ethanol to diethylether and water. The addition of small amount of water caused a marked drop in the isoamylene conversion and in the etherification rate compared to pure ethanol.

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