SORET EFFECT IN DILUTE AQUEOUS ALKALINE EARTH AND NICKEL CHLORIDE SOLUTIONS AT 25 degree C.

被引：0
|
作者：
Petit, C.J. [1 ]
Hwang, M.-H. [1 ]
Lin, J.-L. [1 ]
机构：
[1] Boston Coll, Chestnut Hill, MA, USA, Boston Coll, Chestnut Hill, MA, USA
来源：
International Journal of Thermophysics | 1985年 / 7卷 / 03期
关键词：
ALKALINE EARTH COMPOUNDS - NICKEL COMPOUNDS - POTENTIOMETERS - Applications - THERMAL DIFFUSION - THERMOELECTRICITY;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The Soret effect in dilute aqueous solutions of alkaline earth and nickel chlorides at 25 degree C has been investigated by the potentiometric method. The molar entropies of transport have been obtained from the measurements of the initial and final (Soret steady-state) thermoelectric powers. The Soret coefficients at 0. 005 M (molarity) have been calculated. The variation of the conventional ionic entropies of transport with the ionic radii is investigated and its possible implications for ionic hydration phenomena are discussed.
引用
收藏
页码：687 / 697
相关论文
共 50 条
  • [31] CORROSION OF TITANIUM ALLOYS IN CONCENTRATED CHLORIDE SOLUTIONS AT TEMPERATURES UP TO 160 degree C.
    Ruskol, Yu.S.
    Viter, L.I.
    Balakin, A.I.
    Fokin, M.N.
    Protection of Metals (English translation of Zaschita Metallov), 1982, 18 (04): : 400 - 403
  • [32] ION ASSOCIATION OF RUBIDIUM CHLORIDE IN AQUEOUS-SOLUTIONS AT 25 DEGREES C
    DUNSMORE, HS
    JALOTA, SK
    PATERSON, R
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 (08): : 1583 - &
  • [33] Solubility prediction of malachite in aqueous ammoniacal ammonium chloride solutions at 25 °C
    Wang, Xi
    Chen, Qiyuan
    Hu, Huiping
    Yin, Zhoulan
    Xiao, Zhongliang
    HYDROMETALLURGY, 2009, 99 (3-4) : 231 - 237
  • [34] EFFECT OF ALKALI AND ALKALINE EARTH METAL CATIONS ON STATE OF RHODIUM CHLORIDE IN AQUEOUS SOLUTION
    BURKOV, KA
    BUSKO, EA
    LILICH, LS
    ZHURNAL NEORGANICHESKOI KHIMII, 1970, 15 (06): : 1601 - &
  • [35] Molar conductance of aqueous solutions of sodium, potassium, and nickel trifluoromethanesulfonate at 25‡C
    S. Erol Okan
    D. C. Champeney
    Journal of Solution Chemistry, 1997, 26 : 405 - 414
  • [36] Pourbaix Diagrams for Nickel in Concentrated Aqueous Lithium Bromide Solutions at 25°C
    Munoz-Portero, M. J.
    Garcia-Anton, J.
    Guinon, J. L.
    Perez-Herranz, V.
    CORROSION, 2007, 63 (07) : 625 - 634
  • [37] APPARENT MOLAL VOLUMES OF SOME AQUEOUS RARE EARTH CHLORIDE AND NITRATE SOLUTIONS AT 25 DEGREES
    SPEDDING, FH
    PIKAL, MJ
    AYERS, BO
    JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (08): : 2440 - &
  • [38] RELATIVE VISCOSITIES OF SOME AQUEOUS RARE-EARTH CHLORIDE SOLUTIONS AT 25DEGREESC
    SPEDDING, FH
    WITTE, DL
    SHIERS, LE
    RARD, JA
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1974, 19 (04): : 369 - 373
  • [39] DENSITIES AND APPARENT MOLAL VOLUMES OF AQUEOUS NICKEL CHLORIDE AT 25-DEGREES-C
    RARD, JA
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (02): : 183 - 185
  • [40] ELECTRODE KINETIC BEHAVIOR OF NICKEL IN DILUTE ACID SOLUTIONS FROM 25-C TO 300-C
    COWAN, RL
    STAEHLE, RW
    MATERIALS PROTECTION, 1969, 8 (12): : 53 - &
12345