SORET EFFECT IN DILUTE AQUEOUS ALKALINE EARTH AND NICKEL CHLORIDE SOLUTIONS AT 25 degree C.

被引：0

作者：

Petit, C.J. ^{[1
]}

Hwang, M.-H. ^{[1
]}

Lin, J.-L. ^{[1
]}

机构：

[1] Boston Coll, Chestnut Hill, MA, USA, Boston Coll, Chestnut Hill, MA, USA

来源：

International Journal of Thermophysics | 1985年 / 7卷 / 03期

关键词：

ALKALINE EARTH COMPOUNDS - NICKEL COMPOUNDS - POTENTIOMETERS - Applications - THERMAL DIFFUSION - THERMOELECTRICITY;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The Soret effect in dilute aqueous solutions of alkaline earth and nickel chlorides at 25 degree C has been investigated by the potentiometric method. The molar entropies of transport have been obtained from the measurements of the initial and final (Soret steady-state) thermoelectric powers. The Soret coefficients at 0. 005 M (molarity) have been calculated. The variation of the conventional ionic entropies of transport with the ionic radii is investigated and its possible implications for ionic hydration phenomena are discussed.

引用

页码：687 / 697

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