Characterization of interfaces of directly bonded silicon wafers: a comparative study of secondary ion mass spectroscopy multiple internal reflection spectroscopy, and transmission electron microscopy

被引:0
作者
Reiche, Manfred [1 ]
Hopfe, Sigrid [1 ]
Goesele, Ullrich [1 ]
Strutzberg, Hartmut [1 ]
Tong, Qin-Yi [1 ]
机构
[1] Max-Planck-Inst fuer, Mikrostrukturphysik, Halle, Germany
来源
Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers | 1996年 / 35卷 / 4 A期
关键词
Annealing - Characterization - Chemical bonds - Crystal growth from melt - Fourier transform infrared spectroscopy - Infrared spectrometers - Interfaces (materials) - Mechanical properties - Physical properties - Secondary ion mass spectrometry - Transmission electron microscopy;
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摘要
The structure and chemistry of interfaces of directly bonded Si/Si wafer pairs after annealing at 1100°C were investigated by secondary ion mass spectroscopy (SIMS), multiple internal reflection spectroscopy (MIRS), and high resolution electron microscopy (HRTEM). Si-O, SiO-H, and Si-Hx bonds are shown to be the main atomic bonds at the interfaces of bonded hydrophilic wafer pairs, whereas Si-Si and Si-Hx bonds are dominant at interfaces of bonded hydrophobic wafer pairs. For bonded hydrophobic wafer pairs a frequency shift of the Si-Hx modes suggest that fluorine is probably present in Si-F&middot &middot &middotH-Si configurations. Strongly oriented SiO-H modes detected in bonded hydrophobic wafer pairs appear to be related to oxide islands at the interface.
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页码:2102 / 2107
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