Electrospray-mass spectrometric studies of selectivity of alkali metal cations extraction by calix[4]arene crowns

被引：0
|
作者：
Allain, F. [1 ]
Virelizier, H. [1 ]
Moulin, C. [1 ]
Jankowski, C.K. [1 ,4 ]
Dozol, J.F. [2 ]
Tabet, J.C. [3 ]
机构：
[1] DCC/DPE/SPCP/LASO, CEA Saclay, BP2, 91191 Gif/Yvette, France
[2] DCC/DESD/SEP, CEA Cadarache, 13108 Saint Paul Lez Durance Cedex, France
[3] Univ. de P. et M. Curie, Paris VI, Lab. Chim. Struct. Organique Biol., UMR 7613, 75252 Paris, France
[4] Dept. de Chimie et Biochimie, Université de Moncton, NB E1A 3E9, Canada
来源：
Spectroscopy | 2000年 / 14卷 / 03期
关键词：
Cesium - Complexation - Crown ethers - Extraction - Ionization - Positive ions - Sodium - Solutions - Stoichiometry;
D O I：
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学科分类号：
摘要：
Electrospray Ionization Mass Spectrometry (ESI/MS) has quickly become a versatile method of qualitative analysis of a wide variety of host-guest complexes formed in solution. However, considerable controversy exists on how ESI spectra quantitatively reflect and compare to the results obtained on these complexes. The extraction of alkali cations from acidic aqueous solutions by nine various calix[4]arenes-crown-6 diluted in NPOE, was studied by using ESI/MS. The stoichiometry of cesium complex and Cs+/Na+ selectivity were evaluated.
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页码：127 / 139
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