MECHANISM OF DEHYDRATION OF TERT-BUTYL ALCOHOL IN PHOSPHORIC ACID SOLUTIONS.

被引：0
|
作者：
Obraztsov, P.A. [1 ]
Vinnik, M.I. [1 ]
机构：
[1] Acad of Sciences of the USSR, Moscow, USSR, Acad of Sciences of the USSR, Moscow, USSR
来源：
Kinetics and Catalysis | 1986年 / 27卷 / 5 pt 2期
关键词：
CATALYSIS - Reaction Kinetics - CATALYSTS - PHOSPHORIC ACID - Solutions;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetic regularities of dehydration of tert-butyl alcohol on deposited phosphoric acid catalyst were studied by the pulsed gas-chromatographic method. Dehydration rate constants at 70 degree C were determined in the range of H//3PO//4 concentrations of 50-80. 4 wt. %. A dehydration mechanism was proposed from the dependence of this constant on the acidity of the medium. This includes the formation of a reactive complex consisting of a molecule of an unprotonated alcohol, a molecule of undissociated H//3PO//4 and a molecule of water.
引用
收藏
页码：1094 / 1097
相关论文
共 50 条
  • [41] Interfacial properties of tert-butyl alcohol solutions and their relation to clathrate formation
    Vasquez, D
    Toro, J
    Lozsán, A
    García-Sucre, M
    Urbina-Villalba, G
    JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (10): : 2649 - 2655
  • [42] Dehydration of tert-butyl alcohol in reactive distillation (vol 32, pg 742, 1999)
    Abella, LC
    Gaspillo, PD
    Itoh, H
    Goto, S
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2000, 33 (02) : 351 - 351
  • [43] TERT-BUTYLATION OF 1-NAPHTHOL WITH TERT-BUTYL ALCOHOL OR TERT-BUTYL CHLORIDE IN PRESENCE OF SULFURIC-ACID OR ZINC CHLORIDE
    MIYATA, T
    HAMADA, T
    HIRASHIM.T
    MANABE, O
    HIYAMA, H
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1973, 31 (10) : 831 - 834
  • [44] Synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol on strong acid cation-exchange resins
    Yang, BL
    Yang, SB
    Yao, RQ
    REACTIVE & FUNCTIONAL POLYMERS, 2000, 44 (02): : 167 - 175
  • [45] Photocatalytic oxidation of gas-phase methyl tert-butyl ether and tert-butyl alcohol
    Preis, S
    Falconer, JL
    Asensio, RD
    Santiago, NC
    Kachina, A
    Kallas, J
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 64 (1-2) : 79 - 87
  • [46] COMBINED PROCESS FOR PRODUCTION OF METHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND METHANOL
    MATOUQ, M
    TAGAWA, T
    GOTO, S
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1994, 27 (03) : 302 - 306
  • [47] Sorption of methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA) to synthetic resins
    Bi, EP
    Haderlein, SB
    Schmidt, TC
    WATER RESEARCH, 2005, 39 (17) : 4164 - 4176
  • [48] Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012
    Francois, A
    Garnier, L
    Mathis, H
    Fayolle, F
    Monot, F
    APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2003, 62 (2-3) : 256 - 262
  • [49] Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012
    A. François
    L. Garnier
    H. Mathis
    F. Fayolle
    F. Monot
    Applied Microbiology and Biotechnology, 2003, 62 : 256 - 262
  • [50] Aqueous phosphoric acid as a mild reagent for deprotection of tert-butyl carbamates, esters, and ethers
    Li, Bryan
    Berliner, Martin
    Buzon, Richard
    Chiu, Charles K. -F.
    Colgan, Stephen T.
    Kaneko, Takushi
    Keene, Nandell
    Kissel, William
    Le, Tung
    Leeman, Kyle R.
    Marquez, Brian
    Morris, Ronald
    Newell, Lisa
    Wunderwald, Silke
    Witt, Michael
    Weaver, John
    Zhang, Zhijun
    Zhang, Zhongli
    JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (24): : 9045 - 9050
12345