The study of polymerization kinetics of methacrylamide by oxidation: Reduction system using potassium permanganate/glycine in aqueous medium

被引：0
|
作者：
机构：
[1] Mirzaei, A.A.
[2] Shaterian, H.R.
[3] Habibi, S.M.
来源：
Mirzaei, A.A. (mirzaei@hamoon.usb.ac.ir) | 1600年 / John Wiley and Sons Inc.卷 / 89期
关键词：
Activation energy - Nitrogen - Oxidation - Potassium compounds - Reaction kinetics - Redox reactions - Sulfuric acid;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The polymerization kinetic of methacrylamide with the KMnO 4/glycine redox system has been investigated volumetrically at 35±0.1°C under nitrogen atmosphere in aqueous sulfuric acid medium in a dimethylsulfoxide/H2O mixture (5% v/v). The rates of polymerization were found to obey the following equation: Rp x [Methacrylamide]1.08[GlycineJ0.44[KMnO4 -]0.46. A glycine end group containing polymethacrylamide was prepared by the MnO4-/glycine redox system under mild conditions. The reaction proceeded with radical mechanism and the overall energy of activation (Ea) was calculated to be 29.87 kJ/mol from the Arrhenius plot in the temperature range 25-50°C. Molecular weight of the polymer was determined by viscometry. © 2003 Wiley Periodicals, Inc.
引用
收藏
相关论文
共 50 条
  • [41] Polymerization of acrylamide using mandelic acid/permanganate redox system in acidic medium
    Bajpai, U.D.N., 1600, (40): : 3 - 4
  • [42] Kinetics of aqueous pyrite oxidation by potassium dichromate - An experimental study
    Chirita, P
    TURKISH JOURNAL OF CHEMISTRY, 2003, 27 (01): : 111 - 118
  • [43] KINETICS AND MECHANISM OF ELECTRON-TRANSFER REACTIONS: OXIDATION OF PYRIDINE BY PERMANGANATE IN AQUEOUS ACID PERCHLORATE MEDIUM
    Agrawal, A.
    Sailani, R.
    Sharma, P.
    Khandelwal, C. L.
    Sharma, P. D.
    OXIDATION COMMUNICATIONS, 2016, 39 (02): : 1273 - 1281
  • [44] KINETICS OF GLYCINE OXIDATION BY POTASSIUM PERSULFATE IN AQUEOUS-SOLUTIONS AND RATE CONSTANTS OF ELEMENTARY STEPS
    CHSHMARITYAN, DG
    BEILERYAN, NM
    MKRTCHYAN, EA
    ARMYANSKII KHIMICHESKII ZHURNAL, 1974, 27 (10): : 819 - 824
  • [45] Oxidation of some 1-aryl ethanols using permanganate in aqueous acetic acid medium: A kinetic study
    Rajendran, P
    Rahiman, KKA
    Nair, TDR
    ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (01) : 395 - 400
  • [46] Kinetics and mechanism of oxidation of D-Galactose and D-Maltose with potassium permanganate in acidic medium by spectrophotometry
    Azmat, Rafia
    Naz, Raheela
    Khalil, Amna
    Uddin, Fahim
    ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (02) : 829 - 837
  • [47] KINETICS OF VINYL POLYMERIZATION INITIATED BY POTASSIUM-PERMANGANATE BETA-HYDROXYBUTYRIC ACID REDOX SYSTEM
    BEHARI, K
    GUPTA, KC
    VERMA, M
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1985, 130 (MAR): : 67 - 80
  • [48] KINETIC-STUDY OF OXIDATION OF L-PHENYLALANINE BY POTASSIUM-PERMANGANATE IN NEUTRAL MEDIUM
    ORDAX, FJA
    ARRIZABALAGA, A
    DEILARDUYA, JIM
    ANALES DE QUIMICA SERIE A-QUIMICA FISICA Y QUIMICA TECNICA, 1984, 80 (03): : 531 - 535
  • [49] Oxidation of alkylarenes using aqueous potassium permanganate under cavitation: comparison of acoustic and hydrodynamic techniques
    Ambulgekar, GV
    Samant, SD
    Pandit, AB
    ULTRASONICS SONOCHEMISTRY, 2005, 12 (1-2) : 85 - 90
  • [50] A KINETIC AND MECHANISTIC STUDY OF THE OXIDATION OF GLYCINE BY PYRIDINIUM CHLOROCHROMATE IN AQUEOUS DMF MEDIUM
    Hiran, B. L.
    Meena, M. L.
    Dangarh, B. K.
    Paliwal, S. N.
    OXIDATION COMMUNICATIONS, 2012, 35 (02): : 362 - 370
12345