STRUCTURE AND PROPERTIES OF A SEGMENTED POLYESTER URETHANE FILLED WITH CARBON BLACK.

被引:0
作者
Kercha, Yu.Yu. [1 ]
Kuz'mina, V.A. [1 ]
Laptii, S.V. [1 ]
Goncharova, L.B. [1 ]
Chumikova, G.N. [1 ]
Grekov, A.P. [1 ]
机构
[1] Acad of Sciences of the Ukrainian, SSR, Inst of Chemistry of, High-Molecular Compounds, Kiev, USSR, Acad of Sciences of the Ukrainian SSR, Inst of Chemistry of High-Molecular Compounds, Kiev, USSR
来源
Soviet progress in chemistry | 1984年 / 50卷 / 03期
关键词
CARBON BLACK - POLYMERS - Fillers;
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摘要
The effect was investigated of carbon black, added to the reaction mixture of a segmented polyester urethane based on oligooxytetramethylene glycol, 4,4**1-diphenylmethane diisocyanate, and 1,4-butanediol, on its structure and complex properties. It was found that addition of filler in the process of PEU synthesis leads to a significant change in its properties by virtue of the fact that the presence of an interface with the solid in the polymer-formation process causes structural disturbances, displayed in loosening of rigid domains, playing the role of nodes of a physical grid in segmented polyurethanes, together with a decrease in molecular mass of the system.
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页码:105 / 108
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