ORGANOMETALLIC POLYMERS.

被引：0

作者：

Pittman, Charles U. ^{[1
]}

Rausch, Marvin D. ^{[1
]}

机构：

[1] Mississippi State Univ, Mississippi,, MS, USA, Mississippi State Univ, Mississippi, MS, USA

来源：

Pure and Applied Chemistry | 1985年 / 58卷 / 04期

关键词：

IRON COMPOUNDS - Synthesis - MONOMERS - Chemical Reactions - POLYMERIZATION - Copolymerization - POLYMERS - Molecular Structure - VINYL RESINS - Reactions;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The homopolymerization kinetics of ( eta **5-vinylCp)W(CO)//3CH//3 and ( eta **5-vinylCp)Cr(CO)//2NO were studied. Copolymerization of several eta **5-vinylCp monomers with styrene, methyl acrylate, acrylonitrile and N-vinylpyrrolidone were conducted using radical initiation. From the reactivity ratios, values of the Alfrey-Price Qe parameters were obtained, illustrating that all of the metallic monomers studied were exceptionally electron rich. Cationic initiation of the ( eta **5-isopropenylCp)-metal type monomers gave low molecular weight homopolymers and copolymers at best. The syntheses of 1,1 prime -bis( beta -aminoethyl)ferrocene and their interfacial polycondensation with both diacid chlorides and diisocyanates was conducted.

引用

页码：617 / 622