Synthesis, characterization and properties of N, N'-bis(6-methyl-2-pyridine-N-oxide)-1, 3-propane and europium and terbium complexes

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作者
Gou, Ruhu [1 ]
Li, Gang [1 ]
Liu, Bo [1 ]
Yang, Rudong [1 ]
Yan, Lan [1 ]
机构
[1] College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
关键词
Emission spectroscopy - Luminescence - Synthesis (chemical) - Terbium compounds - Europium compounds;
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摘要
A new ligand, N, N'-Bis(6-methyl-2-pyridine-N-oxide)-1, 3-propane (L), and some binary lanthanide complexes (Ln=Eu3+, Tb3+) were synthesized and characterized in detail. The composition of the binary complexes was determined as LnL(NO3)3. They are 1:1 electrolytes in DMF. The complexes have strong characteristic line fluorescence emission spectra, and it is also found that TbL(NO3)3 complex has stronger luminescence intensity than EuL(NO3)3 in solid state and in methanol.
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页码:21 / 24
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