Metal complexes of biologically important ligands, CXL [1]. Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids

被引：0

作者：

Koch, Daniela ^{[1
]}

Beck, Wolfgang ^{[1
]}

机构：

[1] Dept. Chem. Ludwig-Maximilians-Univ., Butenandtstr. 5-13, D-81377 Munchen, Germany

来源：

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences | 2001年 / 56卷 / 12期

关键词：

Iridium compounds - Metal complexes - Ruthenium compounds - Palladium compounds - Rhodium compounds;

D O I：

10.1515/znb-2001-1204

中图分类号：

学科分类号：

摘要：

o-Fluorophenyl glycine and alanine, 2-thienyl glycine and alanine form with dinuclear, chloro bridged metal complexes the chiral N,0-chelates (arene)M(Cl)(NH2CHRCO2) (M = Ru, Rh, Ir; arene = cymene, Cp*) and (R3P)(Cl)M(NH2CHRCO2) (M = Pd, Pt) as mixtures of diastereoisomers or cis/trans-isomers, respectively.

引用

页码：1271 / 1280