The effect of solvent on the structure of the transition metal complexes in solution

被引：0

作者：

Erenburg, S.B. ^{[1
]}

Bausk, N.V. ^{[1
]}

Zemskova, S.M. ^{[1
]}

Mazalov, L.N. ^{[1
]}

机构：

[1] Institute of Inorganic Chemistry RAS, Lavrentiev av.3, Novosibirsk 630090, Russia

来源：

Journal of Synchrotron Radiation | 1999年 / 6卷 / 03期

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摘要：

CdK EXAFS, ZnK and CuK EXAFS and XANES spectra were measured for solutions of cadmium, zinc and copper dialkyldithiocarbamates in organic solvents with varying donating abilities: benzene, pyridine, tributylphosphine and for some model compounds. The parameters of the local surroundings of the Cd, Zn and Cu atoms for complex forms in solutions were determined using EXAFS spectroscopy. Spatial structure models of the complex forms in a metal chelate - nonaqueous solvent system are suggested.

引用

页码：582 / 584