Electrical properties of polyaniline films formed in acid with and without Cs+ ions in the electrolyte

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作者
Biaggio, S.R. [1 ]
Oliveira, C.L.F. [1 ]
Aguirre, M.J. [1 ]
Zagal, J.H. [1 ]
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[1] Universidade Federal de Sao Carlos, Sao Carlos, Brazil
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| 1600年 / Chapman & Hall Ltd, London, United Kingdom卷 / 24期
关键词
Electrochemical impedance spectroscopy - Polyaniline films;
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摘要
The effect of Cs+ ions added to the electrolyte for polyaniline films electrosynthesized in 0.1 M aniline/0.5 M H2SO4 was investigated. Some properties of PANI films, such as the capacitance, the ohmic resistance and the charge-transfer resistance were obtained using electrochemical impedance spectroscopy. It was found that Cs+ ions used during PANI synthesis change its morphology, with a consequent increase in capacitance and conductivity, and a decrease in charge-transfer resistance.
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