INFRARED STUDIES OF SURFACE SPECIES OF 1,2-EPOXYPROPANE ON METAL OXIDES.

被引：0

作者：

Miyata, Hisashi ^{[1
]}

Toda, Yoshio ^{[1
]}

Kubokawa, Yutaka ^{[1
]}

机构：

[1] Univ of Osaka Prefecture, Sakai, Jpn, Univ of Osaka Prefecture, Sakai, Jpn

来源：

Bulletin of the University of Osaka Prefecture, Series A Engineering and Natural Sciences | 1986年 / 35卷 / 01期

关键词：

SPECTROSCOPY; INFRARED; -; Applications;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Surface species of 1,2-epoxypropane adsorbed on various metal oxides have been studied by infrared spectroscopy. It was found that MgO, TiO//2, alumina, and silica-alumina produced two types of alkoxide species by scission of the alpha -bond (O-CH) or beta -bond (O-CH//2) of 1,2-epoxypropane at rather low temperature. At higher temperature carboxylate species and polymer are present predominantly. A limiting number of sites on metal oxides participates in isomerization of epoxypropane.

引用

页码：57 / 62

共 3 条

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