Electrostatics of metal-solution interface (phenomenological description)

被引:0
|
作者
Salem, R.R. [1 ]
机构
[1] High Chemical Coll RAS, Moscow, Russia
来源
Surface Investigation X-Ray, Synchrotron and Neutron Techniques | 2000年 / 15卷 / 04期
关键词
Capacitance - Electrolytes - Electronic density of states - Electrostatics - Metals - Surfaces;
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学科分类号
摘要
Differential capacitance of the metal-electrolyte solution interface is usually described by a model of two series-connected capacitors. However, each capacitor can have a leakage resistance. This work demonstrates how one can avoid uncertainties arising under substitution of the model of series-connected capacitors by their electric equivalents for the description of the metal-solution interface and confirm it experimentally.
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页码:685 / 689
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