Raman scattering study of the orientational dynamics of the methyl bromide

被引：0
|
作者：
Kocot, A. [1 ]
Wrzalik, R. [1 ]
机构：
[1] Institute of Physics, University of Silesia, Katowice, Poland
来源：
Journal of Molecular Liquids | 1996年 / 69卷 / 9 SPEC. ISS.期
关键词：
D O I：
10.1016/S0167-7322(96)90017-3
中图分类号：
学科分类号：
摘要：
Raman band shapes of the v3 vibration in methyl bromide have been studied in the temperature range 183 K to 333 K. The isotropic and anisotropic part of the band were determined and then used to calculate spectral density of the rotational contribution. The integrated spectral density of the rotational contribution has been found to satisfy the second moment criterion. Both rotational correlation function and angular velocity correlation function have been determined and analysed.
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页码：235 / 242
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