Synthesis and characterisation of charge transfer salts based on Au(dcdmp)2 and TTF type donors

被引：0

作者：

Belo, D. ^{[1
]}

Morgado, J. ^{[1
]}

Lopes, E.B. ^{[1
]}

Santos, I.C. ^{[1
]}

Rabaca, S. ^{[1
]}

Duarte, M.T. ^{[1
]}

Gama, V. ^{[1
]}

Henriques, R.T. ^{[1
]}

Almeida, M. ^{[1
]}

机构：

[1] Instituto Tecnologico e Nuclear, Sacavem, Portugal

来源：

Synthetic Metals | 1999年 / 102卷 / 1 -3 pt 2期

关键词：

Charge transfer - Crystallization - Diffusion in solids - Electric conductivity measurement - Electron transport properties - Gold compounds - Synthesis (chemical) - Thermoelectricity;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The synthesis of the Bu4N salt of the Au complex with 2,3-dicyano 5,5-dimercaptopyrazine, Bu4N [Au(dcdmp)2], is reported. Charge transfer salts with TTF were obtained by electrocrystallisation and diffusion techniques in acetonitrile. Both techniques afford needle shaped crystals with electrical conductivity of the order of 200 S/cm. 1:1 mixed stack semiconducting compounds were obtained with ET, and one other also semiconducting, with TMTSF.

引用

页码：1751 / 1752

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