Synthesis and characterisation of charge transfer salts based on Au(dcdmp)2 and TTF type donors

被引：0

作者：

Belo, D. ^{[1
]}

Morgado, J. ^{[1
]}

Lopes, E.B. ^{[1
]}

Santos, I.C. ^{[1
]}

Rabaca, S. ^{[1
]}

Duarte, M.T. ^{[1
]}

Gama, V. ^{[1
]}

Henriques, R.T. ^{[1
]}

Almeida, M. ^{[1
]}

机构：

[1] Instituto Tecnologico e Nuclear, Sacavem, Portugal

来源：

Synthetic Metals | 1999年 / 102卷 / 1 -3 pt 2期

关键词：

Charge transfer - Crystallization - Diffusion in solids - Electric conductivity measurement - Electron transport properties - Gold compounds - Synthesis (chemical) - Thermoelectricity;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The synthesis of the Bu4N salt of the Au complex with 2,3-dicyano 5,5-dimercaptopyrazine, Bu4N [Au(dcdmp)2], is reported. Charge transfer salts with TTF were obtained by electrocrystallisation and diffusion techniques in acetonitrile. Both techniques afford needle shaped crystals with electrical conductivity of the order of 200 S/cm. 1:1 mixed stack semiconducting compounds were obtained with ET, and one other also semiconducting, with TMTSF.

引用

页码：1751 / 1752

共 50 条

[31] Synthesis and crystal engineering of new halogenated tetrathiafulvalene (TTF) derivatives and their charge transfer complexes and radical ion salts
Batsanov, AS
Bryce, MR
Chesney, A
Howard, JAK
John, DE
Moore, AJ
Wood, CL
Gershtenman, H
Becker, JY
Khodorkovsky, VY
Ellern, A
Bernstein, J
Perepichka, IF
Rotello, V
Gray, M
Cuello, AO
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (09) : 2181 - 2191
[32] Structure and electronic properties of BEDT-TTF and it's charge transfer salts
French, SA
Catlow, CRA
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (01) : 39 - 49
[33] Synthesis and characterization of two charge-transfer salts based on Keggin-type polyoxometalates and morpholinebiguanide
Z. J. Ku
S. R. Jin
H. B. Zhou
Russian Journal of Coordination Chemistry, 2009, 35 : 195 - 199
[34] Synthesis and structure of charge transfer salts of tetrathiafulvalene (TTF) and tetramethyl-TTF with 2,4,7-trinitro and 2,4,5,7-tetranitro-9-fluorenone
Reinheimer, Eric W.
Galan-Mascaros, J. R.
Dunbara, Kim R.
SYNTHETIC METALS, 2009, 159 (1-2) : 45 - 51
[35] Novel charge transfer salts of BEDT-TTF with metal oxalate counterions
Rashid, S
Turner, SS
Day, P
Light, ME
Hursthouse, MB
Guionneau, P
SYNTHETIC METALS, 2001, 120 (1-3) : 985 - 986
[36] Synthesis and Characterization of Two Charge-Transfer Salts Based on Keggin-Type Polyoxometalates and Morpholinebiguanide
Ku, Z. J.
Jin, S. R.
Zhou, H. B.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (03) : 195 - 199
[37] Charge-transfer salts based on Lindqvist and Keggin polyoxoanion acceptors and ferrocenyl cationic donors
Xiong, Jun
Niu, Yujuan
Xu, Haisheng
Cao, Guolei
Liu, Bin
Hu, Huaiming
Xue, Ganglin
NEW JOURNAL OF CHEMISTRY, 2012, 36 (05) : 1224 - 1230
[38] SYNTHESIS OF NEW DONORS CONTAINING 2 TTF MOIETIES
TATEMITSU, H
NISHIKAWA, E
SAKATA, Y
MISUMI, S
SYNTHETIC METALS, 1987, 19 (1-3) : 565 - 568
[39] Synthesis and Crystal Structure of Charge-Transfer Salt (TTF)[Pt(mnt)2]
Wang, Shi
He, Wenrui
Huang, Wei
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (03) : 430 - 433
[40] Understanding the Charge Transfer at the Interface of Electron Donors and Acceptors: TTF-TCNQ as an Example
Park, Changwon
Atalla, Viktor
Smith, Sean
Yoon, Mina
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (32) : 27266 - 27272

← 1 2 3 4 5 →