Nanostructured hybrid materials from aqueous polymer dispersions

被引:204
作者
Castelvetro, Valter [1 ,2 ]
De Vita, Cinzia [1 ]
机构
[1] Dipartimento di Chimica, University of Pisa, 56126 Pisa
[2] INSTM, Research Unit of Pisa, 56126 Pisa
关键词
Emulsion polymerization; Nanoparticle; Organic-inorganic hybrid; Reactive latex; Sol-gel;
D O I
10.1016/j.cis.2003.10.017
中图分类号
学科分类号
摘要
Various methods for preparing hybrid nanostructures from aqueous polymer dispersions were studied. Styrene or acrylate homo- and co-polymer core latex particles need to be modified with a reactive comonomer. Accurate control over pH and process conditions is required to avoid latex coagulation or, in case of organic particles with uniform composition, incipient intraparticle crosslinking. It is observed that these nanostructures can be useful precursors of hollow spheres with well-defined size and composition.
引用
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页码:167 / 185
页数:18
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