The problem of reduction of chlorine-organics agents at bleaching is with solved transition to technology soft ECF at well-balanced charges of chlorine dioxide and hydrogen peroxide. On faculty of pulp and paper technology of Arkhangelsk state technical university for a number of years the researches on optimization of bleaching conditions of hardwood pulp are carried out. As a result of researches the bleaching scheme on technology soft ECF has been developed. The offered scheme includes a stage of preliminary acid processing by a water solution of chlorine dioxide.