Structural solid state study of ethylene copolymers and terpolymers using high resolution 13C n.m.r

被引:0
|
作者
Grenier-Loustalot, Marie-Florence [1 ]
机构
[1] Univ de Pau et des Pays de l'Adour, France
来源
Polymer communications Guildford | 1990年 / 31卷 / 08期
关键词
Acrylics--Morphology - Polyethylenes--Morphology - Polyvinyl Acetates - Terpolymers--Structure;
D O I
暂无
中图分类号
学科分类号
摘要
A solid phase CP MAS 13C n.m.r. study was carried out on a series of ethylene co- and terpolymers of ethylene. Based on several selective experiments, it was shown that at levels of 5 and 10% branches were completely rejected into the amorphous and interface parts of the polymer. At concentrations higher than 20%, however parts of the branches are found in the crystalline part, regardless of the thermal history of the polymer.
引用
收藏
页码:329 / 332
相关论文
共 50 条
  • [31] Investigations on Ferroelectric Liquid Crystal by High Resolution TEM and Solid State 13C NMR
    Zhao, Yongxia
    Yang, Yanqin
    Xu, Jingwei
    Yang, Wei
    Zhou, Yunchun
    Jiang, Zijiang
    Ge, Xin
    JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (45): : 13175 - 13180
  • [32] High-resolution solid-state 13C NMR studies of poly[(R)-3-hydroxybutyric] acid
    Nozirov, F
    Fojud, Z
    Klinowski, J
    Jurga, S
    SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2002, 21 (3-4) : 197 - 203
  • [33] 15N and 13C high-resolution solid-state NMR study of the polymorphism of the L-enantiomer of N-benzoylphenylalanine
    Olejniczak, Sebastian
    Mikua-Pacboczyk, Justyna
    Hughes, Colan E.
    Potrzebowski, Marek J.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (06): : 1586 - 1593
  • [34] C-13 N M R SPECTRA OF STYRENE-BUTADIENE COPOLYMERS ON SOLID SAMPLES
    CONTI, F
    DELFINI, M
    SEGRE, AL
    POLYMER, 1974, 15 (08) : 539 - 541
  • [35] High-resolution solid-state NMR studies on uniformly [13C,15N]-labeled ubiquitin
    Seidel, K
    Etzkorn, M
    Heise, H
    Becker, S
    Baldus, M
    CHEMBIOCHEM, 2005, 6 (09) : 1638 - 1647
  • [36] Structural analysis of core-shell type polymer particles composed of poly(butyl acrylate) and poly(methyl methacrylate) by high-resolution solid- state 13C n.m.r. spectroscopy
    Takeda Chemical Industries, Yodogawa, 532, Osaka, Japan
    不详
    Polymer, 12 (3323-3329):
  • [37] Structural analysis of core-shell type polymer particles composed of poly(butyl acrylate) and poly(methyl methacrylate) by high-resolution solid-state 13C n.m.r. Spectroscopy
    Ishida, M
    Oshima, J
    Yoshinaga, K
    Horii, F
    POLYMER, 1999, 40 (12) : 3323 - 3329
  • [38] Solid state 13C NMR study of ethylene ionomers: Crystalline phase after heat treatment
    Asano, Atsushi
    Matsukawa, Takayuki
    Nakazawa, Chikako
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [39] High resolution solid state C-13 NMR study of PEN
    Guo, M
    Zachmann, HG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 318 - POLY
  • [40] Structural study of syndiotactic polypropylene gel by solid-state high resolution C-13 nmr
    Nakaoki, T
    Hayashi, H
    Kitamaru, R
    POLYMER, 1996, 37 (21) : 4833 - 4839