Structural solid state study of ethylene copolymers and terpolymers using high resolution 13C n.m.r

被引：0
|
作者：
Grenier-Loustalot, Marie-Florence [1 ]
机构：
[1] Univ de Pau et des Pays de l'Adour, France
来源：
Polymer communications Guildford | 1990年 / 31卷 / 08期
关键词：
Acrylics--Morphology - Polyethylenes--Morphology - Polyvinyl Acetates - Terpolymers--Structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A solid phase CP MAS 13C n.m.r. study was carried out on a series of ethylene co- and terpolymers of ethylene. Based on several selective experiments, it was shown that at levels of 5 and 10% branches were completely rejected into the amorphous and interface parts of the polymer. At concentrations higher than 20%, however parts of the branches are found in the crystalline part, regardless of the thermal history of the polymer.
引用
收藏
页码：329 / 332
相关论文
共 50 条
  • [1] STRUCTURAL SOLID-STATE STUDY OF ETHYLENE COPOLYMERS AND TERPOLYMERS USING HIGH-RESOLUTION C-13 NMR
    GRENIERLOUSTALOT, MF
    POLYMER COMMUNICATIONS, 1990, 31 (08): : 329 - 332
  • [2] A structural study of (ethylene-vinyl alcohol) copolymers by high-resolution solid-state 13C NMR
    Kanekiyo, M
    Kobayashi, M
    Ando, I
    Kurosu, H
    Amiya, S
    POLYMER, 2000, 41 (07) : 2391 - 2404
  • [3] Protonation state of adamantanamine template after high-silica zeolite synthesis, studied by 13C solid-state n.m.r
    Hearmon, R.Angus, 1600, (10):
  • [4] HIGH RESOLUTION SOLID STATE 13C n. m. r. OF CANADIAN PEATS.
    Hammond, Terry E.
    Cory, David G.
    Ritchey, William M.
    Morita, H.
    1687, (64):
  • [5] INFLUENCE OF CRYSTALLIZATION CONDITIONS ON THE LOCATION OF SIDE-CHAIN BRANCHES IN ETHYLENE COPOLYMERS AS STUDIED BY HIGH-RESOLUTION SOLID-STATE 13C N. M. R.
    Laupretre, F.
    Monnerie, L.
    Barthelemy, L.
    Vairon, J.P.
    Sauzeau, A.
    Roussel, D.
    1600, (15):
  • [6] Variable temperature solid state 13C NMR study of copolymers of ethylene and A-olefins.
    Guo, MM
    Cheng, SZD
    Quirk, RP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U358 - U358
  • [7] Solid-state 13C n.m.r. study on miscibility of polyoxymethylene/terpenephenol blends
    Research Cent, Daicel Chemical Ind Ltd, Himeji Hyogo 671-12, Japan
    Polymer, 25 (5569-5575):
  • [8] The crystalline structures of ethylene-dimethylaminoethyl methacrylate copolymers as studied by solid-state high-resolution 13C NMR spectroscopy
    Lin, WX
    Zhang, QJ
    Yang, G
    Chen, Q
    JOURNAL OF MOLECULAR STRUCTURE, 2002, 602 : 185 - 190
  • [9] SOLID STATE HIGH RESOLUTION 13C NMR STUDY OF CHINESE MUDSTONE KEROGENS
    赵丕裕
    孙尧俊
    吴泰琉
    王力平
    朱家祥
    李淑贞
    Science in China,SerB., 1992, Ser.B.1992 (09) : 1121 - 1132
  • [10] Structural characterization of drawn (ethylene-vinyl alcohol) copolymer by high-resolution solid-state 13C NMR
    Kurosu, H
    Fukushima, K
    Matsuo, M
    Ando, I
    Amiya, S
    JOURNAL OF MOLECULAR STRUCTURE, 2002, 602 : 233 - 237
12345