Polymorphism of Trimeric Perfluoro-orfto-phenylene Mercury, [Hg(o-C6F4)]3

被引：0
作者：
Haneline, Mason R. [1 ]
Gabbaï, François P. [1 ]
机构：
[1] Chemistry Department, Texas A&M University 3255 TAMU, Texas 77843-3255, College Station
来源：
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences | 2004年 / 59卷 / 11-12期
关键词：
Mercury; Metallophilic Interactions; Polymorphism; Stacking; van der Waals Interactions;
D O I：
10.1515/znb-2004-11-1218
中图分类号：
学科分类号：
摘要：
Three new modifications of trimeric perfluoro-ortho-phenylene mercury (2) have been investigated by single crystal X-ray diffraction. In each of these modifications, the molecules of 2 form extended stacks. Within each stack, the successive molecules are parallel and separated by approximately 3.3 - 3.4 Å. The packing observed in the different structures is rationalized on the basis of secondary mercury-π interactions, mercuriophilic interactions and electrostatic interactions. Altogether, little preference is given for one particular type of interaction. The packing appears to be dominated by non-directional van der Waals interactions between molecules of 2 which are largely aromatic and whose overall polarizability is magnified by relativistic effects at the mercury(II) centers. © 1946 – 2014: Verlag der Zeitschrift für Naturforschung. All rights reserved.
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页码：1483 / 1487
页数：4
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