Heterometallic Osmium-Mercury Chain Structures Linking Two {Os3(CO}10(ae-X)} Subunits (X = Cl, Br, I): Syntheses and Molecular Structures of [{Os3(CO)10(ae-X)}2(ae4-Hg) ] (X = Cl, I), [{Os3(CO)10(ae-Cl)}2{ae-Hg Os(CO)4$ RTBC@2], and cis-[Os(CO)4{(ae-Hg)Os3(CO)10(ae- @Cl)}2$ /]

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Inorg Chem | / 10卷 / 2092期

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[21] Synthesis of Triosmium Clusters with Amino Acid Ligands: Crystal Structure of (ae-H)Os3(ae-NHCH(CH3)CO2Et)(CO)10
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[22] MOLECULAR-STRUCTURES OF H2OS3(CO)10, H(SC2H5)OS3(CO)10 AND (OCH3)2OS3(CO)10
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[23] Addition of diphenyl diselenide (PhSeSePh) to the clusters [Os3(CO)10(μ-dppm)] and [(μH)Os3(CO)8{Ph2PCH2P(Ph)C6H4}]:: X-ray structures of [Os2(CO)4(μ-SePh)2(μ-dppm)], [Os3(CO)6(μ-CO)(μ-Se)2(μ-C6H4)(μ-dppm)] and two isomers of [Os3(CO)8(μ-SePh)2(μ-dppm)]
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[26] Reactions of [(μ-H)Os3(CO)10(μ-OMe)] and [(μ-H)Os3(CO)9(μ-OMe)(MeCN)] with dppm, dppe, dppp, and PPh2H:: X-ray crystal structures of [(μ-H)Os3(CO)8(μ-OMe)-(μ2-η2-dppm)] and [(μ-H)Os3(CO)9(μ-OMe)(PPh2H)]
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[29] Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)
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