Adsorption and decomposition of triethylphosphine (TEP) and tertiarybutylphosphine (TBP) on GaP(001) studied by HREELS and TPD

被引：0

作者：

Kaneda, G. ^{[1
]}

Takeuchi, T. ^{[1
]}

Murata, J. ^{[1
]}

Sanada, N. ^{[1
]}

Fukuda, Y. ^{[1
]}

机构：

[1] Shizuoka Univ, Hamamatsu, Japan

来源：

Applied Surface Science | 1997年 / 121-122卷

关键词：

Adsorption - Chemisorption - Decomposition - Electron energy loss spectroscopy - Molecular structure - Single crystals - Surface phenomena - Surface structure - Temperature programmed desorption;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

We find that TEP is adsorbed molecularly and TBP is partially dissociated at RT. Some of the TEP molecules on the surface are desorbed and the others are decomposed into C2H4 and H2, evolving from the surface. The desorption peak of the TEP molecule is increased in intensity under hydrogen ambience. For TBP, the TPD peaks for C4H9 radical and C4H8 are found. The peaks of C4H9 radical and C4H8 are increased and decreased in intensity, respectively, under hydrogen ambience. The decomposition mechanisms of TEP and TBP on the GaP(001) surface are discussed.

引用

页码：245 / 248