HYDROGENATION REACTION MECHANISM OF SUMIYOSHI COAL.

被引：0
|
作者：
Maekawa, Yosuke
Yoshida, Ryoichi
Ishi, Tadao
Takeya, Gen
机构：
来源：
Nenryo Kyokaishi | 1980年 / 59卷 / 09期
关键词：
COAL; -; Japan;
D O I：
10.3775/jie.59.9_732
中图分类号：
学科分类号：
摘要：
Japan's Sumiyoshi coal was hydrogenated under 220-230 kg/cm**2 hydrogen pressure at 400 degree C with a red mud-sulfur catalyst and without vehicle oil. The nominal reaction time was changed from 4 to 155 minute. The reaction product was fractionated by n-hexane and benzene into five fractions, including oil 1, oil 2, asphaltene 1, asphaltene 2 and organic benzene insolubles. The structural parameters of each fraction were calculated by NMR (nuclear magnetic resonance) spectroscopy and elemental composition. Salient features of the hydrogenation reaction are discussed.
引用
收藏
页码：732 / 739
相关论文
共 50 条
  • [1] Models for the Hydrogenation of Bituminous Coal.
    Huettinger, K.J.
    Kirrmann, H.
    Erdoel und Kohle, Erdgas, Petrochemie vereinigt mit Brennstoff-Chemie, 1980, 33 (06): : 267 - 271
  • [2] HYDROGENATION OF THE PRODUCTS OF THE REDUCTION AND EXTRACTION OF COAL.
    Ekaterinina, L.N.
    Andreeva, A.I.
    Artemova, N.I.
    Golubeva, V.R.
    Goldenko, N.L.
    Nedoshivin, Yu.N.
    Solid Fuel Chemistry, 1986, 20 (01) : 63 - 68
  • [3] STUDY OF THE ROLE OF METHANOL IN THE CATALYTIC HYDROGENATION OF COAL.
    Taraban'ko, V.E.
    Ivanchenko, N.M.
    Beregovtsova, N.G.
    Korniets, E.D.
    Kuznetsov, P.N.
    Kuznetsov, B.N.
    Solid Fuel Chemistry, 1986, 20 (06) : 71 - 75
  • [4] STUDY OF THE INFLUENCE OF METHANOL ON THE CATALYTIC HYDROGENATION OF COAL.
    Taraban'ko, V.E.
    Beregovtsova, N.G.
    Ivanchenko, N.M.
    Kornietz, E.D.
    Kuznetsov, P.N.
    Solid Fuel Chemistry, 1985, 19 (04) : 71 - 76
  • [5] REACTION-MECHANISM OF COAL HYDROGENATION .3. EFFECT OF COAL TYPE
    OUCHI, K
    OHE, S
    MAKABE, M
    ITOH, H
    FUEL, 1985, 64 (10) : 1391 - 1393
  • [6] Resins in coal. Studies in the composition of coal.
    Francis, W
    Wheeler, RV
    JOURNAL OF THE CHEMICAL SOCIETY, 1926, : 1410 - U9
  • [7] Fractionation and Analysis of Asphaltenes Obtained during Hydrogenation Liquefaction of Coal.
    Stefanova, Maja D.
    Lazarov, Lazarin
    Acta Montana, 1985, (73): : 99 - 114
  • [8] Newer views and works on the tracts of the extraction, swelling and hydrogenation of the coal.
    Moehrle, E
    ANGEWANDTE CHEMIE, 1935, 48 : 0509 - 0513
  • [9] INFLUENCE OF STRUCTURAL PARAMETERS ON THE MECHANISM OF COMBUSTION OF COAL.
    Ben-Aim, R.I.
    International chemical engineering, 1987, 27 (01): : 70 - 75
  • [10] MECHANISM OF COAL HYDROGENATION
    WELLER, S
    CLARK, EL
    PELIPETZ, MG
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1950, 42 (02): : 334 - 336
12345