One-dimensional ion-conductive columnar liquid crystals incorporating ionic liquids

被引：0

作者：

机构：

[1] Shimura, Harutoki

[2] Yoshio, Masafumi

[3] Mukai, Tomohiro

[4] Ohno, Hiroyuki

[5] Kato, Takashi

来源：

Shimura, H. | 1600年 / Society of Polymer Science期

关键词：

Theoretical; (THR); -; Experimental; (EXP);

D O I：

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摘要：

New columnar liquid crystals have been prepared by mixing fan-shaped molecules 1 having hydroxy groups with ionic liquids 2. The interactions between the hydroxyl moieties and the ionic liquids induce and stabilize the columnar liquid crystalline assemblies. Ionic liquids are self-assembled in the center of columns, and they form one-dimensional ion-transporting channels. The hydrocarbon moieties of fan-shaped molecules function as ion insulators. Macroscopic orientation of the self-assembled columns is achieved by shearing the materials, resulting in higher ionic conductivities along the direction of the columnar axis.

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