Carbon-fluorine bond activation coupled with carbon-carbon bond formation at iridium. Confirmation of complete kinetic diastereoselectivity at the new carbon stereocenter by intramolecular trapping using vinyl as the migrating group

被引：0

作者：

Hughes, Russell P. ^{[1
]}

Laritchev, Roman B. ^{[1
]}

Zakharov, Lev N. ^{[2
]}

Rheingold, Arnold L. ^{[2
]}

机构：

[1] Department of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, NH 03755, United States

[2] University of California, San Diego, CA 92093-0358, United States

来源：

Journal of the American Chemical Society | 2005年 / 127卷 / 17期

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D O I：

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摘要：

引用

页码：6325 / 6334

共 38 条

[31] New chiral cyclopentadienylrhenium lewis acids featuring fluorinated triarylphosphanes and enhanced acceptor abilities - An unusual carbon-fluorine bond activation in a metal coordination sphere
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Gladysz, J.A.
2001, Wiley-VCH Verlag
[32] New chiral cyclopentadienylrhenium Lewis acids featuring fluorinated triarylphosphanes and enhanced acceptor abilities - An unusual carbon-fluorine bond activation in a metal coordination sphere
Mohr, W
Stark, GA
Jiao, HJ
Gladysz, JA
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (04) : 925 - 933
[33] Mechanistic investigation of vinylic carbon-fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF
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Clot, Eric
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JOURNAL OF FLUORINE CHEMISTRY, 2010, 131 (11) : 1122 - 1132
[34] Carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation in eta(5)-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; Crystal structures of [M(eta(5)-C(5)Me(5))Cl{(C6F5)(2)PCH2CH2P-(C6F5)(2)}](BF4-)-B-+ (M=Rh or Ir)
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Saunders, GC
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (15): : 3215 - 3220
[35] Carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation in eta5-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; crystal structures of [M(eta5-C5Me5)Cl{(C6F5)2PCH$ -2$/CH2 P(C6F5)2}]+BF4- (M = Rh or Ir)
J Chem Soc Dalton Trans, 15 (3215):
[36] Remarkable regioselectivity in the reaction between [(η5-C5Me4H)RhCl(μ-Cl)]2 and (C6F5)2PCH2CH2P(C6F5)2:: synthesis of a chiral-at-metal rhodium complex cation via carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation
Atherton, MJ
Holloway, JH
Hope, EG
Saunders, GC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 558 (1-2) : 209 - 212
[37] Coupling multiple benzylic activation of simple arenes by CpFe+ with multiple alkene metathesis using Grubbs catalysts:: An efficient carbon-carbon bond formation strategy leading to polycycles, cyclophanes, capsules, and polymeric compounds and their CpFe+ complexes
Martinez, V
Blais, JC
Bravic, G
Astruc, D
ORGANOMETALLICS, 2004, 23 (04) : 861 - 874
[38] STEREOSELECTIVE SYNTHESIS OF BOTH (E)-1,2,4-HEPTATRIEN-6-YNES AND (Z)-1,2,4-HEPTATRIEN-6-YNES - FORMATION OF AN ALPHA,3-DEHYDROTOLUENE BIRADICAL, TRAPPING BY AN INTRAMOLECULAR CARBON CARBON DOUBLE-BOND, AND DECAY OF THE RESULTING NEW BIRADICAL VIA AN INTRAMOLECULAR ROUTE
ANDEMICHAEL, YW
GU, YG
WANG, KK
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (03): : 794 - 796

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