MODEL FOR A SUPPORTED LIQUID-PHASE CATALYST WITH A VOLATILE SOLVENT.

被引：0

作者：

Glick III, John H. ^{[1
]}

Butt, John B. ^{[1
]}

Dranoff, Joshua S. ^{[1
]}

机构：

[1] Northwestern Univ, Evanston, IL, USA, Northwestern Univ, Evanston, IL, USA

来源：

Industrial and Engineering Chemistry Research | 1987年 / 26卷 / 07期

关键词：

CARBON MONOXIDE - Oxidation - ETHYLENE - Oxidation - SOLVENTS - Evaporation;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The use of a supported liquid-phase catalyst for the low-temperature oxidation of carbon monoxide and ethylene has recently been investigated experimentally. The catalyst in this case is a supported Wacker process type catalyst, a solution of palladium and copper salts in water. At reaction conditions the solvent (water) is volatile and, consequently, evaporation and condensation of solvent can occur, depending on the condition of the reactor feed. A steady-state model which accounts for the evaporation and condensation of solvent has been developed and applied to the oxidation of carbon monoxide and found to be in good qualitative agreement with observed trends.

引用

页码：1441 / 1448