Vacancy defects in as-polished and in high-fluence H+-implanted 6H-SiC detected by slow positron annihilation spectroscopy

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作者
Barthe, M.-F. [1 ]
Desgardin, P. [1 ]
Henry, L. [1 ]
Corbel, C. [1 ]
Britton, D.T. [1 ]
Kögel, G. [2 ]
Sperr, P. [2 ]
Triftshäuser, W. [2 ]
Vicente, P. [3 ]
Dicioccio, L. [4 ]
机构
[1] CERI, CNRS, 3A rue de la Fárollerie, FR-45071 Orláans, France
[2] Universität der Bundeswehr München, INF, DE-85577 Neubiberg, Germany
[3] NOVASiC, Savoie Technolac, Arche Bât. 4, BP 267, FR-73375 Le Bourget du Lac, France
[4] CEA/LETI, 17 rue des Martyrs, FR-38041 Grenoble, France
关键词
Chemical mechanical polishing - Energy gap - Ion implantation - Ionization - Positron annihilation spectroscopy - Protons - Silicon carbide;
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摘要
The vacancy defects in near surface region are investigated in n-type 6H-SiC after polishing or low-energy-proton implantation using slow-positron-beam-based positron annihilation spectroscopy. Measuring the momentum distribution of annihilating electron-positron pairs by Doppler broadening spectroscopy we detect an about 100 nm thick vacancy-defects layer under the surface of mechanically polished wafers. No damaged layer is detected after mechano-chemical finishing. Measuring positron lifetime as a function of temperature, we show that neutral and negatively-charged vacancy clusters exist in the track region of low-energy proton-implanted 6H-SiC(H). Depending on annealing, they give rise to positron lifetimes of 257 ± 2 ps, 281 ± 4 ps and 345 ± 2 ps, respectively. By comparison with theory, the 257 ps and 280 ps are attributed to (VC-VSi) 2 and (VC-VSi)3 clusters, respectively. The (VC-VSi)3 cluster has likely an ionization level near the middle of the bandgap. © 2002 Trans Tech Publications.
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页码:493 / 496
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