Study of deep polymerization of dimethyl-diallyl ammonium chloride in dilute solutions using the dynamic-mechanical spectroscopy method

被引：0

作者：

Yanovskii, Yu.G. ^{[1
]}

Topchiyev, D.A. ^{[1
]}

Barancheyeva, V.V. ^{[1
]}

Malkanduyev, Yu.A. ^{[1
]}

Kabanov, V.A. ^{[1
]}

机构：

[1] USSR Acad of Sciences, Russia

来源：

Polymer science USSR | 1988年 / 30卷 / 06期

关键词：

Chemical Reactions--Reaction Kinetics - Monomers--Polymerization - Rheology--Mathematical Models;

D O I：

10.1016/0032-3950(88)90225-0

中图分类号：

学科分类号：

摘要：

Rheological analysis (dynamic mechanical spectroscopy) was used to give a fairly complete description of kinetic and structural-mechanical characteristics of high conversion polymerization of dimethyldiallylammonium chloride in dilute solutions in a relatively wide range of variation of monomer and initiator concentrations. Analytical formulae were derived which link rheological and kinetic parameters of the reaction system during polymerization. A physical model was proposed for structure-formulation in polymerization in dilute solutions, including stages of M increase and the formation of a fluctuation branching network. Parameters of this model were quantitatively evaluated.

引用

页码：1280 / 1288