Infrared spectroscopic studies of adsorption on alkali halide surfaces- 1

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作者
SMART RS
SHEPPARD N
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来源
| 1971年 / 320卷 / 1543期
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ADSORPTION - HYDROCHLORIC ACID;
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摘要
An infrared spectroscopic study of the adsorption of hydrogen halides HCl, HBr, and HI on alkali- metal chlorides, bromides and iodides has shown the presence of a dominant surface species involving hydrogen bonding between the hydrogen halide molecule and a surface anion. In favorable cases it has been possible to measure all three vibration frequencies of the surface complex X- H. . . Y- (X and Y halogen atoms) in the infrared and far infrared regions.
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页码:417 / 436
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